期刊
ORGANIC LETTERS
卷 10, 期 23, 页码 5409-5412出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol8023133
关键词
-
资金
- French Research Ministry
- Universite Paul Cezanne
- Centre National de]a Recherche Scientifique (CNRS)
We propose an asymmetric synthesis of functionalized cyclopentanoids bearing up to four stereogenic centers from easily accessible nitroalkenes and unsaturated aldehydes. The overall sequence includes an enantioselective organocatalytic Michael addition and a [3 + 2]-heterocyclization between an in situ generated silyInitronate and the unactivated double bond. Finally, the fused isoxazoline can be further transformed to various cyclopentanoids.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据