期刊
ORGANIC LETTERS
卷 10, 期 4, 页码 545-548出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol702890s
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资金
- NCRR NIH HHS [RR016544, SIG-1-510-RR-06307] Funding Source: Medline
Click chemistry is used to construct ligand scaffolds for a series of chiral diphosphites. Enantioselectivity as high as 97% ee is obtained using these click ligands in rhodium-catalyzed asymmetric hydrogenation. Control experiments and spectroscopic data suggest that a 16-membered PP-macrocyclic Rh(I) chelate is formed.
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