期刊
ORGANIC LETTERS
卷 10, 期 12, 页码 2509-2512出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol800774c
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资金
- NIGMS NIH HHS [GM 69704] Funding Source: Medline
Readily available, air/moisture-stable orthoplatinated triarylphosphite catalyzes the addition reactions of arylboronic acids with aldehydes with the catalyst loading as low as 0.01%. It also cataylzes a new tandem reaction of arylboronic acids with alpha,beta-unsaturated aldehydes to form 1,3-diaryl-1-propanols. Our study provides a new paradigm for the application of orthoplatinated triarylphosphites, and may pave the road to develop other Pt(II) catalysts for such addition reactions and other tandem reactions with such addition reactions as part of the reaction sequence.
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