期刊
ORGANIC LETTERS
卷 10, 期 18, 页码 3933-3936出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol801478y
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资金
- Chinese Academy of Sciences
- National Natural Science Foundation of China [20625308]
A magnetically separable palladium catalyst was simply synthesized through a wet impregnation incorporating palladium nanoparticles and superparamagnetic Fe3O4 nanoparticles in KBH4 solution, which is a highly efficient catalyst for the carbonylative Sonogashira coupling reaction of aryl iodides with terminal alkynes under phosphine-free conditions. This catalyst is completely magnetically recoverable due to the super paramagnetic behavior of Fe3O4 and can be reused with sustained selectivity and activity.
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