期刊
ORGANIC LETTERS
卷 10, 期 21, 页码 5055-5058出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802018r
关键词
-
资金
- Robert A. Welch Foundation [Y-1362]
- NIH [GM065503]
- NSF [CHE-9601771, CHE-0234811]
The first total synthesis of the Leucetta alkaloid calcaridine A is described based on a biosynthetic postulate. Application of an oxidative rearrangement of a 4,5-disubstituted imidazole leads to the formation of both calcaridine A and epi-calcaridine A. An X-ray crystal structure determination on the latter has allowed the assignment of the relative configuration of the epimeric natural product and calcaridine A by extrapolation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据