期刊
ORGANIC LETTERS
卷 10, 期 17, 页码 3789-3792出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol801469h
关键词
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资金
- Ministerio de Educacion y Ciencia [SAF2007-61015]
- Consolider Ingenio 2010 [CSD2007-00006]
- Xunta de Galicia [GRC2006/132]
- Spanish MEC
An efficient tandem ring-closing dienyne metathesis of dienynes derived from cyclohex-2-enone affords the [5.3.1] carbon framework characteristic of taxanes in a single-step process. Further stereoselective functionalizations of the resulting [5.3.1] carbon framework lead to an advanced intermediate in a novel synthetic strategy for taxane analogs.
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