期刊
ORGANIC ELECTRONICS
卷 15, 期 4, 页码 850-857出版社
ELSEVIER
DOI: 10.1016/j.orgel.2014.01.016
关键词
Polymer light-emitting diodes; Aminoalkyl-functionalized polyfluorenes; Excimer; High work-function cathode
资金
- Natural Science Foundation of China [21125419, 50990065, 51010003, 51073058]
- Ministry of Science and Technology, China (MOST) National Research Project [2009CB623601, 2009CB930604]
- Guangdong Natural Science Foundation [S2012030006232]
- Research Fund for the Doctoral Program of Higher Education of China [20120172140001]
A family of aminoalkyl functionalized blue-, green- and red-emitting polyfluorene based copolymers were synthesized by Suzuki copolymerization. Dibenzothiophene-S, S-dioxide-3,7-diyl (FSO), 2,1,3-benzothiadiazole (BT) and 4,7-di-2-thienyl-2,1,3-benzothiadiazole (DTBT) were incorporated into the backbone of copolymers as blue, green and red chromophores, respectively. It was realized that for all these aminoalkyl functionalized copolymers, the thermal stabilities, UV-vis absorption and electrochemical properties are not affected by molar ratio of aminoalkyl side groups. However, the increased amino-groups content can induce the formation of excimer in FSO based blue-emitting copolymer, which in turn leaded to broadened photoluminescence and electroluminescence spectra along with decreased emission efficiency. In contrast, device based on green and red-emitting copolymers exhibited stable emission, and device performance improved progressively with the enhanced content of aminoalkyl co-monomers. Comparing to the copolymers without aminoalkyl side chains, aminoalkyl functioned materials exhibited distinctly improved device performances for the application as emissive layer in light emitting diodes using high work-function Al as cathode due to the formation of interfacial dipoles that can facilitate electron injection. The maximum luminous efficiency of 3.28, 7.31 and 0.79 cd A (1) was achieved based on copolymers BFN1, GFN15 and RFN15, respectively with device architecture of ITO/PEDOT:PSS/PVK/copolymer/Al. These results indicate that aminoalkyl functionalized copolymers can have great potential for the application as efficient light-emitting layer with high work-function/air-stable cathode. (C) 2014 Elsevier B.V. All rights reserved.
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