期刊
ORGANIC ELECTRONICS
卷 14, 期 10, 页码 2392-2400出版社
ELSEVIER
DOI: 10.1016/j.orgel.2013.06.001
关键词
Organic solar cells; Schottky junction; Bulk heterojunction; Organic photovoltaics; Small molecule
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Waterloo Institute for Nanotechnology (WIN) Nanofellowship
- NSERC Alexander Graham Bell Canada Graduate Scholarship
- Ontario Graduate Scholarship
- WIN Nanofellowship
Schottky junction organic solar cells (OSCs) employ a high work-function anode and an active layer comprised of fullerene and low concentrations of donor. In this study, the roles of the donor material and the donor-acceptor mixing ratio in Schottky junction OSCs are explored. The results show that the high short circuit current (J(sc)) seen in Schottky junction OSCs at low donor concentrations arises primarily from photocurrent contributions from charge-transfer intermolecular states in C-60 aggregates. These aggregates absorb light at 400-600 nm and are thus well matched to the solar spectrum. The presence of the donor molecules is shown to be necessary for the dissociation of the C-60 aggregate excitons, which ultimately allows for enhanced photocurrents. The exciton dissociation process is governed primarily by the highest occupied molecular orbial (HOMO) energy level difference between the donor and C-60, and is only efficient when this difference is large enough for the energetically favorable transfer of holes from C-60 to the donor material. Increasing the donor concentration beyond a certain threshold hinders C-60 aggregate formation and thus removes its contribution to photocurrent completely. Furthermore, the V-oc is shown to be strongly influenced by the choice of donor material, indicating that it is not set by the Schottky junction barrier height as previously thought. In spite of this influence on V-oc, the choice of donor in the active layer does not appear to play a significant role in the extraction of holes from the Schottky junction organic solar cells. Optimized chlorine indium phthalocyanine (ClInPc) doped C-70 Schottky cells were fabricated to demonstrate a peak power conversion efficiency of 3.6%. (C) 2013 Elsevier B.V. All rights reserved.
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