期刊
ORGANIC ELECTRONICS
卷 14, 期 6, 页码 1477-1482出版社
ELSEVIER
DOI: 10.1016/j.orgel.2013.03.003
关键词
Metal based transparent cathode; Titanium oxide; Tungsten oxide; Inverted organic solar cell
资金
- EEWS Research Project of the Office of the 348 KAIST EEWS Initiative [EEWS-2012-N01120012]
- Center for Advanced Soft Electronics under the Global Frontier Research Program
- Ministry of Education, Science and Technology, Korea
- National Research Foundation of Korea (NRF) [2011-0001540, 2012-002216, 2012-0014495]
- Ministry of Education, Science, and Technology
- Ministry of Science, ICT & Future Planning, Republic of Korea [N01130018, KINC01] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2011-0031638] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We demonstrate cathodic multilayer transparent electrodes based on a ZnS/Ag/TiOx (ZAT) structure for ITO-free inverted organic solar cells. A quality solution-based TiOx layer is adopted as an inner dielectric layer to modify the effective work function of Ag, ensuring the ZAT electrode works as a cathode. The effect of the TiOx layer is seen on the open-circuit voltage of a solar cell incorporating this layer, increasing to 900 mV from 600 mV in the case of a cell with a bare Ag layer for a bulk-heterojunction of poly[N-9 ''-hepta-decanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (PCDTBT) and [6,6]phenyl C-70-butyric acid methyl ester (PCBM70). The results of a joint theoretical and experimental study indicate that the photocurrent of a ZAT-based solar cell can be significantly enhanced by carefully balancing the optical-spacer and cavity-resonance effects, both of which are modulated by the thickness of the WO3 layer used as a hole-collection layer at the top anode side. ZAT-based inverted solar cells with an optimized structure exhibit a power conversion efficiency as high as 5.1%, which is comparable to that of the ITO-based equivalent. (C) 2013 Elsevier B. V. All rights reserved.
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