期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 17, 期 7, 页码 1714-1717出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02059k
关键词
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资金
- SERB, India [EMR/2014/000207]
- IIT Gandhinagar
The first alpha-alkylation of alpha,beta,gamma,delta-unsaturated aldehydes is achieved under mild reaction conditions. Several alpha,beta,gamma,delta-unsaturated aldehydes and diarylcarbinols are successfully tested for the synthesis of MBH-type alpha-alkylated products with an excellent regioselectivity. Simple pyrrolidine is efficiently used as a catalyst to achieve a perfect E/Z selectivity of the alpha-alkylated products.
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