期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 40, 页码 7346-7350出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02111b
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资金
- Indian Institute of Technology Madras [CHY/16-17/840/RFIR/ANBA]
- IIT Madras
- CSIR, New Delhi
Cp*Co(iii)-catalysed selective alkylation of directed C-H bonds of arenes and heteroarenes has been accomplished employing donor-acceptor carbenes, derived from -diazocarbonyl compounds. The developed method allows ready access to various substituted -(hetero)aryl--arylacetic acid derivatives in good to excellent yields. Synthetic utility was also shown through the synthesis of a substituted indole derivative, an anticancer agent.
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