期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 12, 期 18, 页码 2969-2978出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00002a
关键词
-
资金
- National Science Foundation of China [21172092, 21372095]
A novel KOAc-promoted alpha-position C-H activation and alkynylation of ethers with alkynyl bromides to 2-alkynyl ethers has been developed under transition-metal-free and simple reaction conditions. In addition, this methodology can also be extended to the vinylation of ethers with vinyl bromides in excellent regio- and stereo-selectivity. A wide range of direct C(sp)-C(sp(3)) and C(sp(2))-C(sp(3)) bonds has been formed through this protocol, which offers a new and alternative route.
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