期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 12, 期 4, 页码 624-636出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41869c
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资金
- Royal Society
- Carnegie Trust for the Universities of Scotland
- EPSRC
- European Research Council under the European Union [279850]
- European Research Council (ERC) [279850] Funding Source: European Research Council (ERC)
Readily prepared 2-arylacetic anhydrides act as convenient ammonium enolate precursors in isothiourea (HBTM-2.1)-mediated catalytic asymmetric intermolecular Michael addition-lactonisation processes, giving diverse synthetic building blocks in good yield with high diastereo- and enantiocontrol (up to 98 : 2 dr and > 99% ee).
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