期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 12, 期 28, 页码 5071-5076出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00682h
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资金
- Charles University Grant Agency [427011]
The highly stereoselective allylic alkylation of Morita-Baylis-Hillman carbonates with beta-ketoesters catalysed by beta-ICD is described. The corresponding products containing two adjacent quaternary and tertiary carbon centers were obtained in good yields with high diastereoselectivity (up to 10 : 1 dr) and enantio-selectivity (up to 95% ee).
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