期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 12, 期 8, 页码 1318-1327出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41911h
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资金
- Council of Scientific and Industrial Research, New Delhi, India
PtCl2 catalysed cascade cyclization of an enediyne-enone system to afford a tetracyclic chromenone is reported, which proceeds through two consecutive highly regioselective 6-endo-dig cyclizations in a single step with the formation of two new C-C bonds and two new rings in excellent yield. A mechanism for this transformation is proposed based on the isolated intermediates.
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