期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 5, 页码 699-708出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob27108g
关键词
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资金
- Spanish MICINN [CTQ2008-04961, CTQ2011-24783]
- Comunidad de Madrid
- European Social Fund [SOLGEMAC-S2009/ENE-1617]
A convergent approach based on Diels-Alder reactions between polycyclic dienes and benzoquinones has emerged as a powerful tool for the construction of helicenequinones and bisquinones. Chemical resolution and asymmetric Diels-Alder reactions with sulfinyl quinones provide direct access to enantiopure derivatives. Biaryl or ferrocenyl dienes can be resolved leading to helicenequinones having additional axial or planar chirality.
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