期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 47, 页码 8175-8178出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41698d
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资金
- National Natural Science Foundation of China [21125206, 21021001]
- National Basic Research Program of China (973 Program) [2010CB833300]
An asymmetric normal-electron-demand aza-Diels-Alder cyclo-addition of 2-aryl-3H-indol-3-ones and 2,4-dienals was explored via trienamine catalysis of a chiral secondary amine. Multifunctional tricyclic polyhydropyrido[1,2-a]indoles were efficiently constructed in good stereoselectivity (up to 92% ee, >19: 1 dr).
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