期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 36, 页码 5998-6002出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob41331d
关键词
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资金
- National Natural Science Foundation of China [21172023, 2102010]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
A highly efficient palladium-catalyzed carbenoid based N-H bond insertion has been developed. The alpha-amino esters were obtained in high isolated yields. Moreover, by choosing a suitable chiral auxiliary, stereoselective Pd-catalyzed N-H insertion has been realized. The chiral a-amino esters were obtained in high yields (up to 91%) and with excellent diastereoselectivities (d.r. > 19 : 1).
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