期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 14, 页码 2241-2244出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob40080h
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We report the in vitro selection of a single-stranded 72-nucleotide DNA enzyme (deoxyribozyme) that catalyzes a Friedel-Crafts reaction between an indole and acyl imidazole in good yield and in aqueous solvent. Appreciable Friedel-Crafts product requires addition of copper nitrate and the deoxyribozyme. We observe deoxyribozyme-mediated bond formation for both in cis and in trans Friedel-Crafts reactions.
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