期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 26, 页码 4379-4382出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob40918j
关键词
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资金
- Department of Science & Technology (DST), India
- CSIR, India
The first example of direct reductive amination (DRA) of ketones with electron-deficient amines (EDA) such as Cbz-, Boc-, EtOCO-, Fmoc-, Bz-, ArSO2-, etc. protected amines have been achieved using catalytic Re2O7/NaPF6. Excellent chemoselectivities as well as diastereoselectivity (for 2-alkyl cyclohexanones) were obtained.
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