期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 14, 页码 2318-2322出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob27457h
关键词
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资金
- national '973' grant [2011CB965300]
- NSFC [21142008]
- Tsinghua University
- Tsinghua University Initiative Scientific Research Program
A unique Rh(II) and Ru(II) catalyzed C-H oxygenation of aryl ketones and other arenes has been developed for the facile synthesis of diverse functionalized phenols. The reaction demonstrates excellent reactivity, regio- and chemoselectivity, good functional group compatibility and high yields. The practicality of this method has been proved by gram-scale synthesis of a few different 2-acylphenols. Its utility has been well exemplified in further applications in heterocycle synthesis and direct modifications of drug Fenofibrate.
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