期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 22, 页码 3756-3760出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob40213d
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资金
- Natural Science and Engineering Research Council (NSERC) of Canada
- Centre for Urban Energy (CUE)
- Ryerson University
The syntheses and physicochemical properties for a series of 2,6-disubstituted-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are reported. The use of chromophores or redox active species as pi-spacers, such as BODIPY, requires the inclusion of a sufficiently conjugated donor in order to achieve appropriate charge separation upon photoexcitation. The information derived from this study offers guiding principles for incorporating strongly absorbing, non-innocent pi-spacers in organic dye design.
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