期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 9, 页码 1446-1450出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob27368g
关键词
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资金
- Japan Science and Technology Agency (ACT-C: Creation of Advanced Catalytic Transformation for the Sustainable Manufacturing at Low Energy, Low Environmental Load)
- Asahi Glass Foundation
- [24105513]
A simple strategy avoiding the decomposition of a naked trifluoromethyl anion to difluorocarbene by a sterically very demanding organo-superbase without the help of a trifluoromethyl anion reservoir such as DMF is reported. The direct non-metallic trifluoromethylation of carbonyl compounds using fluoroform in the presence of t-Bu-P4 base afforded trifluoromethyl alcohols in high yields.
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