期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 11, 期 2, 页码 248-251出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob27044g
关键词
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资金
- NSFC [20902012, 91027008]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1117]
- STCSM [09ZR1402700, 10PJ1401200]
Pillar[5]arenes with introverted amino groups were produced through aminolysis. X-ray analysis demonstrated that the intramolecular hydrogen bonding induced the amino group toward the inner space of the cavity. The kinetic studies and molecular modelings revealed that the hydrogen bonding also contributed to the acceleration of the aminolysis through stabilizing the intermediate.
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