期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 10, 期 1, 页码 83-89出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob05899a
关键词
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资金
- NSFC [21002043, 20932003, 90813012]
- National S&T Major Project of China [2009ZX09503-017]
The salen-Ti complex catalyzed cyanation of nitroolefins was accomplished via the silyl nitronate intermediate for the synthesis of chiral beta-nitronitriles with e.r. up to 92 : 8 and high yields (up to 90%). The catalyst also kept a high turnover frequency at room temperature. The yield and enantioselectivity of the protocol were slightly affected even in a 10 mmol scale.
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