期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 10, 期 44, 页码 8774-8777出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob26339d
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资金
- DST (New Delhi)
- CSIR (New Delhi)
- UGC (New Delhi)
- DST
A convenient, facile, and one-pot methodology for the synthesis of alpha-carbolines from Baylis-Hillman (BH) acetates, involving three steps (reactions), (1) mono alkylation of 2-nitroarylacetonitriles with BH-acetates, (2) reduction of nitro group into amino group using Fe/AcOH and (3) formation of two (five and six membered) rings, is presented. This methodology is successfully applied to the synthesis of bioactive alkaloid neocryptolepine.
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