期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 10, 页码 3948-3953出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob05111c
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资金
- University of Tasmania
- School of Chemistry
- Thomas Crawford Foundation
- Faculty of Science Engineering and Technology
The partial reduction of pyrroles is not a common practice even though it offers a potential route to pyrroline building blocks, commonly used for synthesis. We have investigated the reduction of 2-acyl-N-sulfonylpyrroles and by varying the hydride source and solvent, achieved a chemoselective reduction, leading to 3-pyrrolines and alkyl pyrroles in high yield.
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