期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 1, 页码 101-104出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00758g
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资金
- ERC
- EPSRC
- Spanish MICINN
- Royal Society
- Engineering and Physical Sciences Research Council [EP/H015418/1] Funding Source: researchfish
- EPSRC [EP/H015418/1] Funding Source: UKRI
Substituted indenes can be prepared after a sequence [1,3] O-acyl shift-hydroarylation-[1,3] O-acyl shift. Each step is catalyzed by a cationic NHC-Gold(I) species generated in situ after reaction between [(IPr) AuOH] and HBF4 center dot OEt2. This interesting silver-free way is fully supported by a computational study justifying the formation of each intermediate.
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