期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 8, 页码 2992-2998出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00807a
关键词
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资金
- Board of Research in Nuclear Sciences (BRNS)
- Department of Atomic Energy (DAE)
- Prospective Research Fund (PRF) [BRNS/2007/38/5)]
A series of 2-(3,5-dimethylpyrazol-1-yl) ethylseleno derivatives has been synthesized. The glutathione peroxidase like catalytic activity of these compounds has been studied in a model system, in which reduction of hydrogen peroxide with dithiothreitol (DTTred), in the presence of an organoselenium compound was investigated by H-1 NMR spectroscopy. All these compounds exhibit GPx like catalytic activities and the catalytic reaction proceeds through a selenoxide intermediate, identified by Se-77{H-1} NMR spectroscopy.
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