期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 11, 页码 4091-4097出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob05275f
关键词
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资金
- Natural Science Foundation of China [20832005, 20925205]
- National Basic Research Program of China (973 Program) [2009CB522300]
- Natural Science Foundation of Yunnan Provincial Science & Technology Department [2010GA014]
In this work, a general and flexible synthetic route towards the synthesis of pyrroloindoline alkaloids was developed. This new strategy features with a palladium mediated sequential arylation-allylation of o-bromoanilides and leads to the construction of oxindoles bearing a full carbon quaternary center. The cheap triphenylphosphine was proved to be a highly effective ligand for this one pot transformation. On the basis of this new method, esermethole and its analogues were synthesized.
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