期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 4, 页码 1054-1060出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00524j
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资金
- State Key Laboratory of Fine Chemicals [KF0801]
- Science Research Foundation of DUT
- DUT
- National Natural Science Foundation of China [20725619, 20836002, 20923006, 21076034]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0711]
A simple and efficient protocol has been developed for the PdCl2-catalyzed ligand-free and aerobic Suzuki reaction of aryl bromides or nitrogen-based heteroaryl bromides with arylboronic acids in good to excellent yields in aqueous ethanol. A systematic investigation on the effect of different atmospheres on the reactivity of the palladium-catalyzed Suzuki reaction has been carried out, the results show that an aerobic atmosphere demonstrates a positive effect on the reactivity of the Suzuki reaction in an aqueous media and a negative effect in a pure organic solvent, which exhibits that the water plays a crucial role for the function of the atmosphere on the palladium-catalyzed ligand-free Suzuki reaction.
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