期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 8, 期 17, 页码 3831-3846出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c005219c
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资金
- National Institutes of Health NIGMS [R01GM084945]
- American Chemical Society [46850-G1]
- University of Illinois at Chicago
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM084945] Funding Source: NIH RePORTER
Transition metal-catalyzed N-atom transfer reactions of azides provide efficient ways to construct new carbon-nitrogen and sulfur-nitrogen bonds. These reactions are inherently green: no additive besides catalyst is needed to form the nitrenoid reactive intermediate, and the by-product of the reaction is environmentally benign N(2) gas. As such, azides can be useful precursors for transition metal-catalyzed N-atom transfer to sulfides, olefins and C-H bonds. These methods offer competitive selectivities and comparable substrate scope as alternative processes to generate metal nitrenoids.
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