期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 8, 期 6, 页码 1431-1437出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b925377g
关键词
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资金
- European Social Fund
- Programme Alban
- European Union Program of High Level Scholarships for Latin America [E07D402519AR]
- Principado de Asturias
- MICINN [CTQ2007-61126]
- EU
Parallel interconnected kinetic asymmetric transformations were performed in order to obtain enantioenriched derivatives starting from a set of racemic or prochiral compounds. Thus, in a one-pot reaction using two redox biocatalysts (a BVMO and an ADH) and a catalytic amount of cofactor that acts as a mediator, enantioenriched ketones, sulfoxides, and sec-alcohols were concurrently obtained in a strict parallel way, minimising the quantity of reagents employed. By selecting the appropriate biocatalysts, this methodology represents a potential tool for performing stereodivergent transformations.
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