期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 8, 期 5, 页码 1188-1193出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b920285d
关键词
-
资金
- Engineering and Physical Sciences Research Council [EP/C010973/1] Funding Source: researchfish
(4E,8E,10E)-9-Methyl-4,8,10-sphingatrienine, a core component of marine sphingolipids, was synthesised for the first time using a copper(I)-mediated 1,2-metallate rearrangement of a lithiated glycal as a key step. It was converted to phalluside-1, a cerebroside isolated from the ascidian Phallusia fumigate. By an analogous route, (4E, 8E)-9-methyl-4,8-sphingadiene was synthesised and converted to Sch II, a cerebroside that induces fruiting body formation in the basidiomycete Schizophyllum commune.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据