期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 7, 期 16, 页码 3208-3211出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b907534h
关键词
-
资金
- Spanish Ministry of Science and Technology [CSD2007-00006]
Two new artificial hemoproteins or hemozymes, obtained by non covalent insertion of Fe(III)-meso-tetra-p-carboxy- and -p-sulfonato-phenylporphyrin into xylanase A from Streptomyces lividans, were characterized by UV-visible spectroscopy and molecular modeling studies, and were found to catalyze the chemo-and stereoselective oxidation of thioanisole into the S sulfoxide, the best yield (85 +/- 4%) and enantiomeric excess (40% +/- 3%) being obtained with Fe(III)-meso-tetra-p-carboxyphenylporphyrin-Xln10A as catalyst in the presence of imidazole as co-catalyst.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据