期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 7, 期 8, 页码 1554-1561出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b817889e
关键词
-
资金
- EPSRC
Chiral, tripodal anion hosts derived from either S-phenylalanine or S-leucine bind D-lactate enantioselectively. The nature of the host-guest interaction has been probed by solution NMR methods and by DFT calculations. The calculations suggest that the D-lactate may form an additional hydrogen bond in the host-guest complex while the L-lactate complex contains an intramolecular hydrogen bond. Anion binding is in competition with host dimerisation, as demonstrated by DOSY and H-1 NMR spectroscopy, and DFT calculations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据