期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 6, 期 3, 页码 468-476出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b716446g
关键词
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The copper complex of a chiral iminopyridine easily prepared from (R)-(-)-fenchone and picolylamine catalyzes the enantioselective Henry (nitroaldol) reaction between nitromethane and alpha-keto esters. Good yields and modest to good enantioselectivities are obtained for a wide range of alpha-keto esters, bearing aromatic, alkyl or alkenyl groups attached to the ketone carbonyl group.
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