期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 6, 期 20, 页码 3673-3680出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b811162f
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [19750029]
- The Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [19750029] Funding Source: KAKEN
The Stevens rearrangement of N-allylic alpha-aryl amino acid-derived ammonium salts and the Sommelet-Hauser rearrangement of N-benzylic alpha-alkyl amino acid-derived ammonium salts are shown to proceed with remarkably high levels of diastereoselectivity. The methods presented in this work provide new routes to optically active alpha-quaternary alpha-aryl amino acid derivatives.
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