Mesozoic molybdenum deposits in the east Qinling-Dabie orogenic belt: Characteristics and tectonic settings

The East Qinling-Dabie orogenic belt accommodates the largest Mo ore district in the world. It contains 8.43 Mt of proven Mo metal reserves which accounts for 66% of the total proven Chinese Mo reserves. The Mo ore district includes 24 deposits and 12 occurrences, with four major types of Mo mineral systems, i.e., porphyry, porphyry-skarn, skarn and hydrothermal veins. The latter can be further subdivided into quartz vein and carbonatite vein types. Although Mo mineralization in the belt began in the Paleoproterozoic (1680 +/- 24 to 2044 +/- 14 Ma), all economically significant deposits were formed during the Mesozoic. Re/Os dating of molybdenite has shown that there are three episodes of Mo mineralization, i.e., Late Triassic (233-221 Ma), Late Jurassic to Early Cretaceous (148-138 Ma) and Early to middle Cretaceous (131-112 Ma). Late Triassic Mo deposits developed as molybdenite-quartz veins and carbonatite vein types. Stable isotope systematics (C, O, S) and high contents of Re and Sr indicate that the carbonatite Mo veins are mantle-derived. Porphyry and porphyry-skarn Mo mineral deposits were formed in the Late Jurassic to Early Cretaceous and Early to middle Cretaceous. The Late Jurassic to Early Cretaceous granite porphyries that are associated with the Mo deposits usually occupy less than 1.5 km(2) at the surface and are situated in the East Qinling area, far west of China's continental margin. On the other hand, the Early to middle Cretaceous batholiths and granite porphyries with associated Mo deposits are located in the Dabieshan area and eastern part of the East Qinling area. The Late Jurassic to Early Creataceous granitoids and related Mo deposits possibly formed in a back-arc extensional setting of the Eurasian continental margin, which was probably triggered by the oblique subduction of the Izanagi plate. The Early to middle Cretaceous batholiths and granite porphyries are linked to the tectonic regime of lithospheric thinning, asthenospheric upwelling and partial melting of the crust, induced by a change in Izanagi Plate motion parallel to the continent margin. In the East Qinling-Dabie belt there are vein type Pb-Zn-Ag deposits surrounding porphyry and/or porphyry-skarn Mo (W) deposits, forming well defined ore clusters. The same spatial arrangement (i.e., porphyry Mo stockworks and outlying Pb-Zn-Ag ore veins) is also observed at the deposit scale. Thus, Mo porphyry stockworks and distal polymetallic veins belong to the same ore system and may reflect an outward temperature decrease from the highly fractionated granite plutons. Both, porphyry stockworks and polymetallic veins, can be used as vectors for further prospecting. (C) 2011 Elsevier B.V. All rights reserved.