High substrate temperature induced anomalous phase transition temperature shift in sputtered VO2 thin films

Vanadium dioxide (VO2) thin films were deposited onto Corning glass substrates by rf reactive inverted cylindrical magnetron sputtering at different substrate temperatures (T-s) ranging from 450 to 600 degrees C. The influence of substrate temperature on the structural and optical properties was systematically investigated. It revealed that the crystallinity of the VO2 films improved significantly with T-s. The substrate temperature to obtain films with transition temperature (T-c similar to 70 degrees C) similar to VO2 bulk single crystal was 450-500 degrees C, while high substrate temperatures from 550 to 600 degrees C tend to shift T-c towards higher temperatures from 75 to 80 degrees C keeping the sharpness of the transition unaltered. Even if the variation of the T-c of VO2 is not dramatic variation from 70 to 80 degrees C with increasing T-s is substantial for undoped VO2 thin films. This sizeable variation of similar to 10 degrees C confirms the tunability of the T-c of VO2 through T-s. (C) 2010 Elsevier B.V. All rights reserved.