期刊
TETRAHEDRON LETTERS
卷 56, 期 25, 页码 3886-3889出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.04.106
关键词
Cuprous oxide nanoparticles; Reusable catalyst; Sonogashira reaction; Intramolecular azide-alkyne cyclization; Reaction in water
资金
- Council of Scientific and Industrial research (CSIR), New Delhi, India
An environmentally benign one-pot procedure has been developed for the syntheses of triazole-fused tetracyclic glycosides in aqueous medium. The two step one-pot synthesis involves Sonogashira reaction between azido-alkynes and aryl halides followed by intramolecular 1,3-dipolar cyclization using cubic cuprous oxide nanoparticles as reusable catalyst, under aerobic condition. The method excludes the use of any surfactants or additional ligands as stabilizing agents. The catalyst could be used up to three recycles without any loss of catalytic activity. The method has a broad perspective for the synthesis of medium size ring systems. (C) 2015 Elsevier Ltd. All rights reserved.
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