期刊
TETRAHEDRON LETTERS
卷 56, 期 23, 页码 3093-3096出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.12.146
关键词
FeCl3; Acylation; 1,3-Diketones; C-C bond cleavage
We describe a novel FeCl3 catalyzed selective acylation of amines involving the C-C bond cleavage of simple 1,3-diketones. The process proceeds efficiently under a neat condition to give structurally diverse amides. Notably, the acylation process displays high selectivity toward amines over hydroxyl functionality. Traditionally difficult aromatic amines and sterically demanding disubstituted amines can engage in the process with high efficiency. (C) 2015 Elsevier Ltd. All rights reserved.
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