期刊
TETRAHEDRON LETTERS
卷 56, 期 8, 页码 1004-1006出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.01.053
关键词
Active zinc; Direct insertion; Aminophenylzinc; Cross-coupling; Aminophenyl ketone
New organozinc reagents, 4-aminophenyl zinc iodide (A) and 3-aminophenyl zinc iodide (B), have been generated easily and effectively by the direct insertion of active zinc to iodoanilines which possess acidic protons. The subsequent coupling reactions of the organozincs with various acid chlorides turned out to be an efficient tool for the preparation of aminophenyl ketones. (C) 2015 Elsevier Ltd. All rights reserved.
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