期刊
TETRAHEDRON LETTERS
卷 56, 期 2, 页码 327-330出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.11.078
关键词
Triterpene; Spirocyclic compound; Claisen rearrangement; Oxidative rearrangement
资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan [19790026]
- NOVARTIS Foundation (Japan) for the Promotion of Science
- Chugai Pharmaceutical Co. Ltd.
- Grants-in-Aid for Scientific Research [19790026, 25450151] Funding Source: KAKEN
The spiroiridal triterpenoids show interesting biological activities, such as a piscicidal activity, PKC activation, and molluscicidal activity. Herein, the first synthesis of the functionalized spiro[4.5]decane skeleton of spiroiridal triterpenoids was accomplished. The characteristic features of the present synthesis are the Claisen rearrangement of 2-(alkenyl)dihydropyran developed by our group and the efficient transformation into the key intermediate (+)-6. (C) 2014 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据