期刊
TETRAHEDRON LETTERS
卷 56, 期 44, 页码 6136-6141出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.09.097
关键词
Palladium catalysis; C-H benzoxylation; Hypervalent iodine reagent
资金
- National Natural Science Foundation of China (NSFC) [21302046]
- Hundred-Talent Program Fund of Hubei University of Technology
A palladium-catalyzed ortho-C-H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates has been developed. The reaction employed the stable and easily accessible hypervalent iodine reagents as both benzoxylate source and oxidant which made the protocol simple and facile. It showed high regioselectivity and good functional group tolerance, and gave the mono-benzoxylation products in moderate to excellent yields. (C) 2015 Elsevier Ltd. All rights reserved.
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