期刊
TETRAHEDRON LETTERS
卷 56, 期 48, 页码 6772-6776出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.10.068
关键词
Electrochemical reduction; Fixation of carbon dioxide; Benzyl alcohols; Phenylacetic acids; One-step formation
资金
- JSPS KAKENHI [25410104]
- Grants-in-Aid for Scientific Research [25410104] Funding Source: KAKEN
Electrochemical direct carboxylation of benzyl alcohols having an electron-withdrawing group on the phenyl ring was successfully carried out by constant current electrolysis using an undivided cell equipped with a platinum plate cathode and a magnesium rod anode in DMF in the presence of carbon dioxide. Reductive cleavage of the C-O bond followed by fixation of carbon dioxide efficiently took place at the benzylic position without any additive to give the corresponding phenylacetic acids in good yields in one step under neutral and mild conditions. (C) 2015 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据