期刊
TETRAHEDRON
卷 71, 期 46, 页码 8725-8731出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.09.054
关键词
Aerobic alcohol oxidation; Supported copper complex; Bipyridine ligand; MCM-41; Heterogeneous catalysis
资金
- National Natural Science Foundation of China [21272044]
- Scientific Research Fund of Education Department of Jiangxi Province [KJLD13022]
A heterogeneous copper(I)-catalyzed aerobic oxidation of primary benzylic and allylic alcohols to aldehydes was achieved under air in EtOH at 50 degrees C in the presence of 5 mol % of MCM-41-immobilized bipyridine copper(I) complex [MCM-41-bpy-CuI] and 5 mol % of 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) using aqueous ammonia as base, yielding a variety of aromatic and alpha,beta-unsaturated aldehydes in good to excellent yields. This heterogeneous copper catalyst can be easily recovered by a simple filtration of reaction solution and reused for at least 10 consecutive trials without any decreases in activity. The use of recyclable heterogeneous copper catalyst and green reagents, such as air as oxidant and ethanol as solvent, made the system attractive for environmentally sustainable processes. (C) 2015 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据