期刊
TETRAHEDRON
卷 71, 期 21, 页码 3528-3534出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.03.027
关键词
Fluorescence spectrum; Indolenium carbocyanine dye; Solid state; Single X-ray structure; Wave deconvolution
The fluorescence intensity of indolenium carbocyanine dyes in the solid state depended on both the alkyl group on the nitrogen atoms in the indolenium rings and the kind of counter anions. The N-propyl derivative having a bis(trifluoromethylsulfonyl)imide anion, whose fluorescence maximum was observed at 657 nm with shoulder peaks, exhibited the highest fluorescence quantum yield of 0.31. The wave deconvolution of fluorescence spectrum indicated three components assigned to the S1,0 -> S0,0, S1,0 -> S0,1, and S1,0 -> S0,2 transitions. The X-ray structure of this compound indicates an isolated monomer-type packing, whereas the other derivatives shows the isolated dimer-type packing or consequent pi/pi stacking. The cyanine dye having the least pi/pi interactions among adjacent cationic fluorophores could exhibit the most intense fluorescence in the solid state. (C) 2015 Elsevier Ltd. All rights reserved.
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