期刊
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
卷 46, 期 7, 页码 968-974出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/15533174.2015.1004417
关键词
1,2,4-triazole; cadmium complex; silver complex; crystal structures; fluorescence properties
Two d(10) complexes [Cd(abt)I-2(H2O)] (1) and [Ag-2(abt)(2)]2(CF3SO3) (2), (abt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) have been obtained and characterized by IR, elemental analysis, and X-ray diffraction single-crystal analysis. Complex 1 is mononuclear and Cd(II) center is five coordinated, while complex 2 possesses a dinuclear structure with coordination number 4 for Ag(I) center. Solid-state fluorescence spectra of 1, 2, and abt were investigated at room temperature.
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