期刊
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
卷 46, 期 4, 页码 534-542出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/15533174.2014.988808
关键词
ruthenium; nanoparticles; titanium(IV) oxide; ammonia-borane; hydrogen
资金
- Presidency of Scientific Research Projects of University of Yuzuncu Yil
Herein, the authors report that TiO2 supported ruthenium nanoparticles (Ru(0)/TiO2) during hydrolysis starting with RuCl3/TiO2 precatalyst act as highly active, long-lived, and reusable nanocatalyst in the hydrogen generation from the hydrolysis of ammonia-borane (NH3BH3) at room temperature. The resulting Ru(0)/TiO2 catalyze hydrogen generation from the hydrolysis of ammonia-borane with an initial turnover frequency value of 200min(-1) at 25 +/- 0.1 degrees C. More importantly, Ru(0)/TiO2 are stable enough to be isolated and bottled as solid material, which can be reused as active catalyst under the identical conditions of the first run.
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